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| 中国新一代飞机关键复合材料实现完全自主保障 |
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| 添加日期：2015-03-17 来源： 阅读次数：974 |
廖子龙，中航复合材料有限责任公司副总工程师，研究员。长期从事树脂基体及预浸料研究工作，多次负责重大课题项目中树脂及预浸料研制，国产碳纤维应用研究。对高性能树脂改性，热熔法预浸料制备工艺与设备等方面进行了系统研究，针对我国碳纤维等增强材料复合材料开展全面研究和验证，突破国产碳纤维复合材料应用的关键技术，在我国新一代直升机上获得应用。先后获得集团科技进步一等奖2项，二等奖3项，三等奖2项，某型机航空报国金奖三等奖，某型直升机设计定型二等功，直升机国产复合材料应用研究及工程化应用项目二等功。
先进复合材料具有比模量、比强度高，抗疲劳、耐腐蚀，可设计性强等性能特点，已在航空装备中得到广泛应用，成为飞机结构最重要的材料之一，其用量成为飞机先进性的重要标志之一。与传统的飞机机体使用的金属材料(如铝合金)相比，复合材料在制造或使用中遭受意外冲击(如冰雹、飞石、装配过程的工具跌落等)时，其内部易出现不易观测到的分层损伤，严重威胁飞机结构的安全。因此，如何提高复合材料的抗冲击损伤能力是复合材料在机翼、机身等主承力结构应用的关键技术之一。
随着复合材料技术的不断发展和飞机结构对复合材料要求的提高，1990年波音公司制定了高韧性碳纤维环氧预浸料标准(BMS8-276)，提出了适合民机主承力结构用复合材料的技术指标体系，大大推动高韧性复合材料技术的发展与应用。随着高强中模碳纤维及与之匹配的高韧性树脂基体等关键技术的突破，高强中模碳纤维增强3900-2、 977-1、8551-7、M91和M21E树脂复合材料等为代表的高韧性复合材料抗冲击损伤能力显著提高，复合材料的CAI值达到310MPa以上，并在飞机主承力结构得到广泛应用。
高韧性预浸料技术体系
目前，航空先进复合材料的主要基体材料是热固性树脂(如用量较多的环氧树脂基体类，双马来酰亚胺基体类)，热固性树脂具有成型工艺性、耐环境性和尺寸稳定性好等优点，传统的热固性树脂基体韧性较差，并遗传给碳纤维复合材料较低的抗冲击损伤能力。
提高碳纤维复合材料抗冲击损伤能力是先进复合材料及应用的关键技术之一，主要核心技术是基体树脂增韧。热固性树脂最有效的增韧方法之一是向树脂基体中加入韧性组分，通过构造所谓的“复相”或“多元”体系的手段达到提高树脂基体体系韧性的目的。传统热固性树脂基体的增韧方法主要是在树脂中加入高性能的热塑性树脂，这种增韧技术通常称之为本体增韧技术，在本体增韧技术基础形成了初、中等韧性热固性树脂。树脂本体增韧技术引入大量热塑性成分后，牺牲了原有热固性树脂良好的黏性，使其工艺性明显“劣化”，预浸料铺敷性下降。此外，树脂化学成分的改变以及固化后相结构的改变，使得增韧树脂新结构的控制非常复杂。
合金塑料供应：
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合金塑料
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型号
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制造商
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PBT/PC
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VYLOPET® EMC320R
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TOYOBO America, Inc.
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PBT+PC
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VYLOPET® EMC330
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TOYOBO America, Inc.
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PC/PBT
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VYLOPET® EMC333
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TOYOBO America, Inc.
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PC+PBT
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VYLOPET® EMC341
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TOYOBO America, Inc.
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PBT/PC
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VYLOPET® EMC355
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TOYOBO America, Inc.
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PBT/PET
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VYLOPET® EMC405A
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TOYOBO America, Inc.
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PBT+PET
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VYLOPET® EMC407
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TOYOBO America, Inc.
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PBT+PC
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VYLOPET® EMC532
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TOYOBO America, Inc.
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PC/PBT
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VYLOPET® EMC545
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TOYOBO America, Inc.
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PBT/PET
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VYLOPET® EMC605P
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TOYOBO America, Inc.
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PBT+PET
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VYLOPET® EMC618P
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TOYOBO America, Inc.
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PC+ABS
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VYTEEN PC/ABS 3016
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Lavergne
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PC/ABS
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VYTEEN PC/ABS 8515
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Lavergne
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PC+ABS
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VYTEEN PC/ABS 8515XF
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Lavergne
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PC/ABS
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VYTEEN PC/ABS FR-NH Colored
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Lavergne
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聚酯合金
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Wah Hong UP WH-8100-BLK D
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Wah Hong Industrial Corp.
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聚酯合金
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Wah Hong UP WH-8100-BLK F
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Wah Hong Industrial Corp.
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聚酯合金
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Wah Hong UP WH-8100-BLK FDA
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Wah Hong Industrial Corp.
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聚酯合金
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Wah Hong UP WH-81TM
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Wah Hong Industrial Corp.
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聚酯合金
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Wah Hong UP WH-8200-BLK
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Wah Hong Industrial Corp.
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聚酯合金
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Wah Hong UP WH-8200-BLK F
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Wah Hong Industrial Corp.
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ASA+AES
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WeatherPro™ Centrex®/ABS SP-6710
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Spartech Plastics
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ABS+ASA+Acrylic
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WeatherPro™ Geloy®/ABS SP-6730
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Spartech Plastics
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ABS+ASA+PMMA
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WeatherPro™ Luran®/ABS SP-6720
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Spartech Plastics
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ABS+Acrylic
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WeatherPro™ Plexiglas® DR®/ABS
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Spartech Plastics
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ABS+PMMA
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WeatherPro™ S
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Spartech Plastics
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PA6+PA66
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Wellamid® GF10-66/6-LI6-NBK4
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Wellman
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PA66/6
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Wellamid® GF33-66/6 XE-BK167A
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Wellman
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PA6+PA66
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Wellamid® GF33-66/6 XE-N
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Wellman
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PA66/6
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Wellamid® GF33-66/6 XE-NBK1
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Wellman
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PA6+PA66
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Wellamid® GF33-66/6 XE-WBK
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Wellman
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PA66/6
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Wellamid® GF43-66/6 XE-BK167A
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Wellman
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PA6+PA66
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Wellamid® GF43-66/6 XE-N
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Wellman
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PA66/6
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Wellamid® GF43-66/6 XE-NBK1
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Wellman
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PA6+PA66
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Wellamid® GF60-66/6 XE-N
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Wellman
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PA66/6
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Wellamid® GF60-66/6 XE-NBK1
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Wellman
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尼龙+PP
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Wellamid® NB1803E-BK
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Wellman
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PC+ABS
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Witcom PC/ABS 2S
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Witcom Engineering Plastics B.V.
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PC/ABS
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Witcom PC/ABS 2S-FR
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Witcom Engineering Plastics B.V.
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PC+ABS
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Witcom PC/ABS 3S
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Witcom Engineering Plastics B.V.
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PC/ABS
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Witcom PC/ABS 3S-FR
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Witcom Engineering Plastics B.V.
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PC+ABS
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Witcom PC/ABS AS
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Witcom Engineering Plastics B.V.
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PC/ABS
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Witcom PC/ABS AS-S
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Witcom Engineering Plastics B.V.
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PC+ABS
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Witcom PC/ABS AS-S-LM
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Witcom Engineering Plastics B.V.
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PC/PE
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Wondel® C CEA
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Nanjing Julong Engineering Plastics Co., LTD
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PC合金
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Wondel® C CR0G4
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Nanjing Julong Engineering Plastics Co., LTD
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PC合金
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Wondel® C CR0K
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Nanjing Julong Engineering Plastics Co., LTD
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PC/ABS
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Wondel® C CSA
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Nanjing Julong Engineering Plastics Co., LTD
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PC+ABS
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Wondel® C CSAH
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Nanjing Julong Engineering Plastics Co., LTD
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PC/ABS
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Wondel® C CSR0
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Nanjing Julong Engineering Plastics Co., LTD
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PC+ABS
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Wondel® C CSR0P
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Nanjing Julong Engineering Plastics Co., LTD
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PC+PBT
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Wondel® C CTA
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Nanjing Julong Engineering Plastics Co., LTD
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PC/ABS
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WONDERLOY® PC-345
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Chi Mei
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PC+ABS
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WONDERLOY® PC-365
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Chi Mei
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PC/ABS
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WONDERLOY® PC-385
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Chi Mei
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PC+ABS
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WONDERLOY® PC-510
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Chi Mei
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PC/ABS
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WONDERLOY® PC-540
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Chi Mei
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PC+ABS
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XANTAR® C CE 407
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Mitsubishi EP
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PC/ABS
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XANTAR® C CF 107
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Mitsubishi EP
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PC+ABS
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XANTAR® C CF 407
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Mitsubishi EP
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PC/ABS
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XANTAR® C CF 447
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Mitsubishi EP
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PC+ABS
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XANTAR® C CM 206
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Mitsubishi EP
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PC/ABS
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XANTAR® C CM 206 U
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Mitsubishi EP
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PC+ABS
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XANTAR® C CM 406
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Mitsubishi EP
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PC/ABS
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XANTAR® C CM 406 U
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Mitsubishi EP
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PC+ABS
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XANTAR® C CM 506
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Mitsubishi EP
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PC/ABS
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XANTAR® C CM 506 U
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Mitsubishi EP
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PC+ABS
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XANTAR® C CM 546
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Mitsubishi EP
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PC/ABS
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XANTAR® C MC 3433
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Mitsubishi EP
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PC+ABS
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XANTAR® C MC 3440
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Mitsubishi EP
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PC/ABS
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XANTAR® C MC 3652
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Mitsubishi EP
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PC+ABS
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XANTAR® C MC 3700
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Mitsubishi EP
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PC/ABS
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XANTAR® C RC 3012
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Mitsubishi EP
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PC+PET
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XANTAR® E EM 605
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Mitsubishi EP
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PC+ABS
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XANTAR® LDS 3710
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Mitsubishi EP
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PC/ABS
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XANTAR® LDS 3720
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Mitsubishi EP
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PC+ABS
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XANTAR® LDS 3722
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Mitsubishi EP
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PC/ABS
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XANTAR® LDS 3724
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Mitsubishi EP
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SPS+Nylon
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XAREC™ N WA 5030
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Idemitsu Chemicals
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SPS+Nylon
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XAREC™ N WA 7020
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Idemitsu Chemicals
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SPS+Nylon
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XAREC™ N WA 7030
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Idemitsu Chemicals
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PBT/PC
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XENOY™ 1102 resin
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SABIC_IP
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PBT+PC
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XENOY™ 1731 resin
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SABIC_IP
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PC/PBT
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XENOY™ 1760 resin
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SABIC_IP
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|
PC/PET
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XENOY™ 2230 resin
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SABIC_IP
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|
PC+PBT
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XENOY™ 5220U resin
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SABIC_IP
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PBT/PC
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XENOY™ 5720U resin
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SABIC_IP
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|
PBT+PC
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XENOY™ 6370 resin
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SABIC_IP
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|
PC/PBT
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XENOY™ 6620 resin
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SABIC_IP
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|
PC+PBT
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XENOY™ 6620U resin
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SABIC_IP
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|
PBT/PC
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XENOY™ CL100 resin
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SABIC_IP
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PBT+PC
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XENOY™ CL100S resin
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SABIC_IP
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|
PC/PBT
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XENOY™ ENH2900 resin
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SABIC_IP
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|
PC+PBT
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XENOY™ HX5600HP resin
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SABIC_IP
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|
PBT/PC
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XENOY™ HX6600HP resin
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SABIC_IP
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|
PBT+PC
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XENOY™ IQ1103 resin
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SABIC_IP
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PC/PBT
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XENOY™ IQ1103R resin
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SABIC_IP
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PC+PBT
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XENOY™ IQ1103U resin
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SABIC_IP
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PBT/PC
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XENOY™ IQ4840 resin
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SABIC_IP
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PBT+PC
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XENOY™ IQNH2900 resin
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SABIC_IP
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PC+聚酯纤维
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XENOY™ X2420 resin
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SABIC_IP
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PC+PET
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XENOY™ X2500UV resin
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SABIC_IP
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PC/PBT
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XENOY™ X4810 resin
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SABIC_IP
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PC+PBT
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XENOY™ X4820 resin
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SABIC_IP
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PBT/PC
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XENOY™ X4830 resin
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SABIC_IP
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PBT+PC
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XENOY™ X4850 resin
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SABIC_IP
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PC/PET
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XENOY™ X4870HH resin
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SABIC_IP
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PC+Polyester
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XENOY™ X5100 resin
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SABIC_IP
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PC+PET
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XENOY™ X5230 resin
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SABIC_IP
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PC/PBT
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XENOY™ X5300WX resin
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SABIC_IP
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PC/PET
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XENOY™ X5410 resin
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SABIC_IP
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PBT+PC+PET
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XENOY™ X5601WX resin
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SABIC_IP
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PC+PET
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XENOY™ X5630Q resin
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SABIC_IP
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PC+聚酯纤维
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XENOY™ X8519 resin
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SABIC_IP
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PC/PET
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XENOY™ XL1339 resin
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SABIC_IP
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PC+PBT
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XYLEX™ 1105 resin
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SABIC_IP
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PC+Polyester
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XYLEX™ HX7509HP resin
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SABIC_IP
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PC+聚酯纤维
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XYLEX™ HX8300HP resin
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SABIC_IP
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PC+Polyester
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XYLEX™ X7200MR resin
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SABIC_IP
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PC+聚酯纤维
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XYLEX™ X7300 resin
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SABIC_IP
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PC+Polyester
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XYLEX™ X7300CL resin
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SABIC_IP
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PC+聚酯纤维
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XYLEX™ X7503 resin
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SABIC_IP
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PC+Polyester
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XYLEX™ X7507 resin
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SABIC_IP
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PC+聚酯纤维
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XYLEX™ X7509HP resin
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SABIC_IP
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PC+Polyester
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XYLEX™ X7519HP resin
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SABIC_IP
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PC+聚酯纤维
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XYLEX™ X8210 resin
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SABIC_IP
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PC+Polyester
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XYLEX™ X8300 resin
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SABIC_IP
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PC+聚酯纤维
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XYLEX™ X8303 resin
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SABIC_IP
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PC+Polyester
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XYLEX™ X8303CL resin
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SABIC_IP
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PC+聚酯纤维
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XYLEX™ X8409AC resin
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SABIC_IP
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PC+Polyester
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XYLEX™ X8419 resin
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SABIC_IP
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Nylon+PPE
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XYRON™ A0210
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Asahi Kasei
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PPE/PA
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XYRON™ AG211
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Asahi Kasei
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PPE+PA
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XYRON™ AG213
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Asahi Kasei
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Nylon+PPE
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XYRON™ AG511
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Asahi Kasei
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PPE/PA
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XYRON™ AG512
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Asahi Kasei
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PPE+PA
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XYRON™ AT600
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Asahi Kasei
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Nylon+PPE
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XYRON™ AT602
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Asahi Kasei
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PPE/PA
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XYRON™ AT610
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Asahi Kasei
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PPS/PPE
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XYRON™ DG043
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Asahi Kasei
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PPS+PPE
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XYRON™ DG141
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Asahi Kasei
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PPS/PPE
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XYRON™ DG235
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Asahi Kasei
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PPS+PPE
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XYRON™ DV166
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Asahi Kasei
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PPE/PP
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XYRON™ EV103
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Asahi Kasei
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PPE+PP
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XYRON™ T0702
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Asahi Kasei
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PPE/PP
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XYRON™ TT520
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Asahi Kasei
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PA6+PA66
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Yuyao PA 011BG20
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Yuyao Tenglong Plastics Co., Ltd.
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PA66/6
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Yuyao PA 011BG30
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Yuyao Tenglong Plastics Co., Ltd.
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PA6+PA66
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Yuyao PA 01MG20
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Yuyao Tenglong Plastics Co., Ltd.
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PA66/6
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Yuyao PA 01MG30
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Yuyao Tenglong Plastics Co., Ltd.
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PA6+PA66
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Yuyao PA 022MC
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Yuyao Tenglong Plastics Co., Ltd.
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PA66/6
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Yuyao PA 02MC
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Yuyao Tenglong Plastics Co., Ltd.
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PA6+PA66
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Yuyao PA 033ML20
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Yuyao Tenglong Plastics Co., Ltd.
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PA66/6
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Yuyao PA 033ML30
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Yuyao Tenglong Plastics Co., Ltd.
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PA6+PA66
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Yuyao PA 03ML20
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Yuyao Tenglong Plastics Co., Ltd.
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PA66/6
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Yuyao PA 03ML30
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Yuyao Tenglong Plastics Co., Ltd.
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PA6+PA66
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Yuyao PA 055ZR16
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Yuyao Tenglong Plastics Co., Ltd.
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PA66/6
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Yuyao PA 055ZR8
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Yuyao Tenglong Plastics Co., Ltd.
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PA6+PA66
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Yuyao PA 05ZR16
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Yuyao Tenglong Plastics Co., Ltd.
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PA66/6
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Yuyao PA 05ZR8
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Yuyao Tenglong Plastics Co., Ltd.
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PC+ABS
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Zhongfa PC/ABS CH-110
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Yuyao Zhongfa Engineering Plastics Co. Ltd.
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PC/ABS
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Zhongfa PC/ABS CH110-FR
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Yuyao Zhongfa Engineering Plastics Co. Ltd.
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PC+ABS
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Zhongfa PC/ABS CL-90
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Yuyao Zhongfa Engineering Plastics Co. Ltd.
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PC/ABS
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Zhongfa PC/ABS CL-90FR
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Yuyao Zhongfa Engineering Plastics Co. Ltd.
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PC+ABS
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Zhongfa PC/ABS CW-100
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Yuyao Zhongfa Engineering Plastics Co. Ltd.
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PC/ABS
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Zhongfa PC/ABS CW-100-FR
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Yuyao Zhongfa Engineering Plastics Co. Ltd.
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PC+ABS
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Zhongfa PC/ABS CW-G20
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Yuyao Zhongfa Engineering Plastics Co. Ltd.
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PA6+PA66
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Zytel® 74G33W BK196
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DuPont
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PA66/6
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Zytel® 74G33W NC010
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DuPont
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PA6+PA66
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Vitamide® TB28GY6548
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Perrite
|
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PA66/6
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Vitamide® TF33
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Perrite
|
|
PA6+PA66
|
Vitamide® TH36BK6752
|
Perrite
|
|
PA66/6
|
Vitamide® TR26
|
Perrite
|
|
PA6+PA66
|
Vitamide® TR36BK6635
|
Perrite
|
|
PA66/6
|
Vitamide® TS10BK8517
|
Perrite
|
|
PA6+PA66
|
Vitamide® TS10NT6164
|
Perrite
|
|
PA66/6
|
Vitamide® TS20RD6369
|
Perrite
|
|
PA6+PA66
|
Vitamide® TS30GY6278
|
Perrite
|
|
PA66/6
|
Vitamide® TS70BK6761
|
Perrite
|
|
PBT+PET
|
Vitaster® UW36NT6757
|
Jackdaw Polymers
|
|
PA6+PA66
|
Vydyne® 75HB NT0679
|
Ascend
|
|
PA66/6
|
Vydyne® 75HF
|
Ascend
|
|
PA6+PA66
|
Vydyne® 85XFS
|
Ascend
|
|
PA66/6
|
Vydyne® 86XFS
|
Ascend
|
|
PA6+PA66
|
Vydyne® 88X
|
Ascend
|
|
PA66/6
|
Vydyne® 88X-D
|
Ascend
|
|
PA6+PA66
|
Vydyne® ECO-315
|
Ascend
|
|
PA66/6
|
Vydyne® R633
|
Ascend
|
|
PA6+PA66
|
Vydyne® R633H01
|
Ascend
|
|
PA66/6
|
Vydyne® R633H05
|
Ascend
|
|
PC/PBT
|
VYLOPET® CA3300
|
TOYOBO America, Inc.
|
|
PC+PBT
|
VYLOPET® CA5310
|
TOYOBO America, Inc.
|
|
PBT/PC
|
VYLOPET® EMC130-20
|
TOYOBO America, Inc.
|
|
PBT+PC
|
VYLOPET® EMC132-01
|
TOYOBO America, Inc.
|
|
PC/PBT
|
VYLOPET® EMC132-02
|
TOYOBO America, Inc.
|
|
PC+PBT
|
VYLOPET® EMC133
|
TOYOBO America, Inc.
|
|
PBT/PC
|
VYLOPET® EMC307
|
TOYOBO America, Inc.
|
|
PBT+PC
|
VYLOPET® EMC310
|
TOYOBO America, Inc.
|
|
PC/PBT
|
VYLOPET® EMC310TU
|
TOYOBO America, Inc.
|
|
PC+PBT
|
VYLOPET® EMC317A
|
TOYOBO America, Inc.
|
|
PC/PBT
|
HiFill® PC/PBT IM 5720 UV BK
|
TP Composites
|
|
|
|
