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| 生物基复合材料新型环保技术是大势所趋 |
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| 添加日期：2015-03-19 来源： 阅读次数：656 |
聚合化合物应用于很多领域，包括汽车、航空和建筑行业。纤维增强型聚合物与未增强型相比，硬度、机械性能、延伸性、弯曲性、抗冲击强度、拉伸强度更为优异。聚合物内部的纤维将塑料紧紧结合在一起，在压力下的抗变形、抗破损性能优异。不过性能优异程度取决于多个方面，包括：纤维的尺寸(长度和宽度)、聚合物内纤维的密度、纤维和聚合物之间的粘合力以及纤维本身缺陷和形变。
由于纤维增强型聚合物被大量应用于大型工业领域，所以自然而然大家就比较关心它们的环境影响。石化基聚合物生产过程中对环境会造成一系列的危害，并且需要大量的石油这一有限资源。纤维本身一般是由玻璃和碳构成，其生产过程中也有自己的隐忧。除环境方面的影响外，复合材料成本也是一个重要因素，玻纤和碳纤本身生产成本就相对比较高，而波动的油价也意味着与之相关的复合材料总体价格也不稳定。成本和环境两方面的担心驱使业界去开发一种新材料，在与当前复合材料机械系性能类似的前提下成本更低，工艺更环保。这种新材料就是天然纤维增强型聚合物，这类聚合物的纤维或聚合物原料或两者都是来自于可再生资源。天然纤维增强型聚合物目前正由积极研发新型复合物的研究者们进行评估。
与传统石油基塑料、玻璃和碳纤维相比，这类复合物的明显优势是生物材料成本更低，而且原料资源可再生，密度也比传统玻纤或碳纤增强型塑料低。不过，要想取代当前使用的某些或所有纤维增强型塑料，必须保证生物基复合材料拥有合理的机械性能。
现在已有的生物基聚合物是从淀粉、糖类、植物油和大豆中提取的。这类塑料已经应用于很多消费领域;然而，对于其在工业领域的应用大家比较保守，因为很多生物基聚合物适用期有限。石油基塑料目前使用的性能增强型天然纤维来在于亚麻、大麻、洋麻剑麻，另外还有几种备选天然纤维如黄麻纤维和椰子纤维。天然纤维增强型的石油基塑料已经应用于汽车领域生产各种内部和非结构性组件，包括杯架、门板和后备箱边线。汽车当前组件如保险杠是由玻纤复合材料制作，它可以使用混合天然和玻纤复合材料代替，后者拥有相似甚至更优异的性能。总体来说，大部分天然纤维增强型复合材料的机械性能略逊于传统材料，不过使用混合纤维将减少对玻纤和碳纤的依赖，极大的降低成本和环境影响。
另外一个担心是天然纤维和生物基聚合物的寿命，在使用寿命方面无论是生物基还是石油基聚合物都要面对这一问题。天然纤维易受水份影响，这将导致纤维膨胀和降解，引起性能下降。降解也会导致产生气味，这对于汽车内部件而言是很严重的问题。此外，生长环境的差异导致天然纤维性能的参差不齐，这也会影响其增强聚合物的性能。不过经过化学处理可以降低天然纤维的吸水性，提高其稳定性。还可使用各种纳米技术涂料提高天然纤维性能。
尽管实现生物基复合材料全面应用于工业领域还需要很长的路要走，但是新型环保技术是大势所趋。生物基纤维和混合复合物所带来的生态和经济好处驱动着一大帮研究机构投入到此类工业和处理技术的研究中，他们志在获得高性能、耐用的生物基纤维增强复合材料，改变这一行业面貌。
合金塑料供应：
|
合金塑料
|
型号
|
制造商
|
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PBT/PET
|
KumhoSunny PBT/PET HEB4051M
|
Shanghai KumhoSunny Plastics Co., Ltd.
|
|
PBT/PET
|
Lupox® SG3250A
|
LG Chem
|
|
PBT/PET
|
Lupox® SG5150
|
LG Chem
|
|
PBT/PET
|
Lupox® SG5200
|
LG Chem
|
|
PBT/PET
|
Lupox® SG5500
|
LG Chem
|
|
PBT/PET
|
Melos PBT PB70 GR30 NL CA 01
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Melos
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PBT/PET
|
Novalloy-B BE2703 (Type K)
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Daicel Polymer Ltd.
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PBT/PET
|
POCAN® DP 4035 000000
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LANXESS
|
|
PBT/PET
|
POCAN® ECO T 3220 000000
|
LANXESS
|
|
PBT/PET
|
POCAN® ECO T 3240 000000
|
LANXESS
|
|
PBT/PET
|
POCAN® T 3150 XF 000000
|
LANXESS
|
|
PBT/PET
|
POCAN® T 7323 000000
|
LANXESS
|
|
PBT/PET
|
POCAN® T 7331 000000
|
LANXESS
|
|
PBT/PET
|
POCAN® T 7391 000000
|
LANXESS
|
|
PBT/PET
|
POLYshine PBT C213 GF15 FR
|
Polykemi
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|
PBT/PET
|
RAMSTER PF321G6
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Polyram
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|
PBT/PET
|
SCHULADUR® A1 GF 30 LW
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A. Schulman
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|
PBT/PET
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SCHULADUR® PCR GF 15 K1947
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A. Schulman
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|
PBT/PET
|
SCHULADUR® PCR GF 20
|
A. Schulman
|
|
PBT/PET
|
SCHULADUR® PCR GF 45
|
A. Schulman
|
|
PBT/PET
|
Sindustris PBT SG3251
|
Sincerity Australia Pty Ltd.
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|
PBT/PET
|
Sindustris PBT SG3251M
|
Sincerity Australia Pty Ltd.
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|
PBT/PET
|
Sindustris PBT SG-5153
|
Sincerity Australia Pty Ltd.
|
|
PBT/PET
|
Sindustris PBT SG5301
|
Sincerity Australia Pty Ltd.
|
|
PBT/PET
|
TAROLOX 2050 W G3
|
Taro Plast
|
|
PBT/PET
|
TAROLOX 2050 W G6
|
Taro Plast
|
|
PBT/PET
|
TechnoDur PBT-PET GF15 black (9970)
|
TechnoCompound
|
|
PBT/PET
|
TechnoDur PBT-PET GF20 black (9967)
|
TechnoCompound
|
|
PBT/PET
|
TechnoDur PBT-PET GF30 black (9964)
|
TechnoCompound
|
|
PBT/PET
|
Tecodur® PB70 GR15 BK002 XA21
|
Eurotec
|
|
PBT/PET
|
Tecodur® PB70 GR20 BK002 TD21
|
Eurotec
|
|
PBT/PET
|
Tecodur® PB70 GR35 NL100 HS01
|
Eurotec
|
|
PBT/PET
|
Tecodur® PB70 GR50 BK002 CA01
|
Eurotec
|
|
PBT/PET
|
TEKALOY™ F50G30
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e-polymers
|
|
PBT/PET
|
Ultradur® B 4040 G10
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BASF
|
|
PBT/PET
|
Ultradur® B 4040 G6
|
BASF
|
|
PBT/PET
|
Ultradur® B 4406 G6 Q113
|
BASF
|
|
PBT/PET
|
VALOX™ 8032U resin
|
SABIC_IP
|
|
PBT/PET
|
VALOX™ 815 resin
|
SABIC_IP
|
|
PBT/PET
|
VALOX™ 830F resin
|
SABIC_IP
|
|
PBT/PET
|
VALOX™ EH7020HF resin
|
SABIC_IP
|
|
PBT/PET
|
VALOX™ ENH8530 resin
|
SABIC_IP
|
|
PBT/PET
|
VALOX™ IQ8280SF resin
|
SABIC_IP
|
|
PBT/PET
|
VALOX™ V8280 resin
|
SABIC_IP
|
|
PBT/PET
|
VYLOPET® EMC405A
|
TOYOBO America, Inc.
|
|
PBT/PET
|
VYLOPET® EMC605P
|
TOYOBO America, Inc.
|
|
PBT/PS
|
PLANAC BSV-130
|
DIC Trading
|
|
PBT/SAN
|
DURANEX® SF733LD
|
Polyplastics Co., Ltd.
|
|
PBT+ASA
|
ALTECH® PBT + ABS A 2020/620 GF 20 UV
|
ALBIS PLASTIC GmbH
|
|
PBT+ASA
|
ALTECH PBT+ASA A 2030/500 GF30 ((PBT+ASA)-GF30, ALBIS Plastic)
|
ALBIS PLASTIC GmbH
|
|
PBT+ASA
|
ALTECH® PBT + ASA A 4212/506 GF3MR9
|
ALBIS PLASTIC GmbH
|
|
PBT+ASA
|
Anjacom® 465-GF15
|
Almaak International GmbH
|
|
PBT+ASA
|
Edgetek™ CY8000 BK003
|
PolyOne Corporation
|
|
PBT+ASA
|
Generic PBT+ASA - Glass Fiber
|
Generic
|
|
PBT+ASA
|
KumhoSunny PBT/ASA HBA5810G
|
Shanghai KumhoSunny Plastics Co., Ltd.
|
|
PBT+ASA
|
KumhoSunny PBT/ASA HBA5820G
|
Shanghai KumhoSunny Plastics Co., Ltd.
|
|
PBT+ASA
|
POCAN® A 3121 000000
|
LANXESS
|
|
PBT+ASA
|
POCAN® A 3131 000000
|
LANXESS
|
|
PBT+ASA
|
RAMLLOY PFS301G6
|
Polyram
|
|
PBT+ASA
|
Romiloy® 5230 GF 20
|
Romira
|
|
PBT+ASA
|
Romiloy® 5240 GF 30
|
Romira
|
|
PBT+ASA
|
SCANBLEND P AP2060 F20
|
Polykemi
|
|
PBT+ASA
|
SCANBLEND P AP2060 F30B
|
Polykemi
|
|
PBT+ASA
|
SCHULADUR® A3 GF 20
|
A. Schulman
|
|
PBT+ASA
|
SCHULADUR® A3 GF 30 FR 1
|
A. Schulman
|
|
PBT+ASA
|
SCHULADUR® A3 GF 30 TS SCHWARZ
|
A. Schulman
|
|
PBT+ASA
|
SLOVASTER® B/A GF 20
|
Plastcom
|
|
PBT+ASA
|
TAROLOX 200 G2
|
Taro Plast
|
|
PBT+ASA
|
TAROLOX 200 G6
|
Taro Plast
|
|
PBT+ASA
|
Tecodur® PB70 GR30 NL MB04
|
Eurotec
|
|
PBT+ASA
|
Ultradur® S 4090 G4
|
BASF
|
|
PBT+ASA
|
Ultradur® S 4090 G4 High Speed
|
BASF
|
|
PBT+ASA
|
Ultradur® S 4090 G6 High Speed
|
BASF
|
|
PBT+ASA
|
Ultradur® S 4090 G6X
|
BASF
|
|
PBT+ASA
|
Ultradur® S 4090 GX
|
BASF
|
|
PBT+PC
|
Anjatech® 010/50-E
|
Almaak International GmbH
|
|
PBT+PC
|
ASHLENE® R3144
|
Ashley Polymers, Inc.
|
|
PBT+PC
|
Badadur® PBT/PC FR V0
|
Bada AG
|
|
PBT+PC
|
Cheng Yu B610
|
Cheng Yu Plastic Company Limited
|
|
PBT+PC
|
ColorRx® PCPB-1000NB
|
LTL Color Compounders, Inc.
|
|
PBT+PC
|
DESLOY™ DSC940B
|
DESCO Co., Ltd.
|
|
PBT+PC
|
DIAMALOY ENGINEERED ALLOYS PC/PBT 627
|
Network Polymers, Inc.
|
|
PBT+PC
|
DURANEX® 702MS
|
Polyplastics Co., Ltd.
|
|
PBT+PC
|
DURANEX® HN7315N/B
|
Polyplastics Co., Ltd.
|
|
PBT+PC
|
Edgetek™ CY4000 BK006
|
PolyOne Corporation
|
|
PBT+PC
|
Edgetek™ CY4000 UV YE703
|
PolyOne Corporation
|
|
PBT+PC
|
Edgetek™ XT XT-100-BU03 Black
|
PolyOne Corporation
|
|
PBT+PC
|
EnCom PC-PBT 1013
|
EnCom, Inc.
|
|
PBT+PC
|
ENVIRON® ENV39-NC400
|
ENVIROPLAS®, Inc.
|
|
PBT+PC
|
ENVIRON® ENV39-NC440
|
ENVIROPLAS®, Inc.
|
|
PBT+PC
|
ENVIRON® ENV39-NC500
|
ENVIROPLAS®, Inc.
|
|
PBT+PC
|
Generic PC+PBT - Glass Fiber
|
Generic
|
|
PBT+PC
|
HiFill® PC / PET 2230 HF UV
|
TP Composites
|
|
PBT+PC
|
HiFill® PC/PBT IM 5720 LE
|
TP Composites
|
|
PBT+PC
|
HiFill® PC/PBT IM 6702
|
TP Composites
|
|
PBT+PC
|
Hybrid B2026IU
|
Entec
|
|
PBT+PC
|
Hybrid B6720
|
Entec
|
|
PBT+PC
|
Jackdaw PC DS20WT6701
|
Jackdaw Polymers
|
|
PBT+PC
|
KumhoSunny PC/PBT HCB9230M
|
Shanghai KumhoSunny Plastics Co., Ltd.
|
|
PBT+PC
|
KumhoSunny PC/PBT HCB9330G
|
Shanghai KumhoSunny Plastics Co., Ltd.
|
|
PBT+PC
|
LNP™ THERMOCOMP™ 9X07430 compound
|
SABIC_IP
|
|
PBT+PC
|
LONOY lonoy 3010
|
Kingfa
|
|
PBT+PC
|
Lucent PC GPCB-120
|
Lucent
|
|
PBT+PC
|
Lucent PC PC/PBT-1212
|
Lucent
|
|
PBT+PC
|
Lucent PC PC/PBT-1422
|
Lucent
|
|
PBT+PC
|
Lucent PC PC/PBT-FR5
|
Lucent
|
|
PBT+PC
|
Lucky Enpla LAY3003R
|
Lucky Enpla Co LTD
|
|
PBT+PC
|
Lupox® HI2303
|
LG Chem
|
|
PBT+PC
|
Lupox® LW5402A
|
LG Chem
|
|
PBT+PC
|
Lupox® TE5000H
|
LG Chem
|
|
PBT+PC
|
Lupox® TE5000SP
|
LG Chem
|
|
PBT+PC
|
Lupox® TE5100
|
LG Chem
|
|
PBT+PC
|
Makroblend® KU2-7912/4
|
Bayer MatSc
|
|
PBT+PC
|
Makroblend® UT3907
|
Bayer MatSc
|
|
PBT+PC
|
Makroblend® UT6007
|
Bayer MatSc
|
|
PBT+PC
|
Michiloy MT11220
|
API Polymers, Inc.
|
|
PBT+PC
|
NEXUS PC/PBT PC/PBT 7820
|
Nexus
|
|
PBT+PC
|
Niloy F30
|
Soredi
|
|
PBT+PC
|
OP - PC/PBT 802-I
|
Oxford Polymers
|
|
PBT+PC
|
Pier One PC/PBT 1102
|
Pier One Polymers, Inc.
|
|
PBT+PC
|
Plaslube® PC / PBT IM 5720 A BK
|
Techmer Lehvoss
|
|
PBT+PC
|
POCAN® C 3230 XF 000000
|
LANXESS
|
|
PBT+PC
|
POCAN® DP C 1502 000000
|
LANXESS
|
|
PBT+PC
|
POLYlux 104 HF
|
Polykemi
|
|
PBT+PC
|
POLYlux MP4010
|
Polykemi
|
|
PBT+PC
|
PTS PCA-30G00
|
Polymer Technology and Services, LLC
|
|
PBT+PC
|
Radici Compounds PC/PBT 501020L
|
RadiciPlastics
|
|
PBT+PC
|
Romiloy® 5720 UV
|
Romira
|
|
PBT+PC
|
Shinblend® A274G20
|
Shinkong Synthetic Fibers Corp.
|
|
PBT+PC
|
Sindustris PBT LW5103F
|
Sincerity Australia Pty Ltd.
|
|
PBT+PC
|
Sindustris PBT LW5403A
|
Sincerity Australia Pty Ltd.
|
|
PBT+PC
|
Sindustris PBT TE5001GU
|
Sincerity Australia Pty Ltd.
|
|
PBT+PC
|
Sindustris PBT TE5001S
|
Sincerity Australia Pty Ltd.
|
|
PBT+PC
|
Sindustris PBT TE5012M
|
Sincerity Australia Pty Ltd.
|
|
PBT+PC
|
Sup-tech CT103
|
Shanghai Suptech Engineering Plastics Co. Ltd.
|
|
PBT+PC
|
TAROLOY 50
|
Taro Plast
|
|
PBT+PC
|
Tecotek® PC40 NL VB02
|
Eurotec
|
|
PBT+PC
|
Triapol® Blends F3 K28 UV NTLA010 BS307
|
Petropol Industry and Trade of Polymers LTDA
|
|
PBT+PC
|
VALOX™ 357 resin
|
SABIC_IP
|
|
PBT+PC
|
VALOX™ 3706 resin
|
SABIC_IP
|
|
PBT+PC
|
VALOX™ 553 resin
|
SABIC_IP
|
|
PBT+PC
|
VALOX™ IQ357U resin
|
SABIC_IP
|
|
PBT+PC
|
VAMPTER C 3028 V0
|
VampTech
|
|
PBT+PC
|
Visiloy™ 2653U2
|
Technical Polymers, LLC
|
|
PBT+PC
|
VYLOPET® EMC132-01
|
TOYOBO America, Inc.
|
|
PBT+PC
|
VYLOPET® EMC310
|
TOYOBO America, Inc.
|
|
PBT+PC
|
VYLOPET® EMC330
|
TOYOBO America, Inc.
|
|
PBT+PC
|
VYLOPET® EMC532
|
TOYOBO America, Inc.
|
|
PBT+PC
|
XENOY™ 1731 resin
|
SABIC_IP
|
|
PBT+PC
|
XENOY™ 6370 resin
|
SABIC_IP
|
|
PBT+PC
|
XENOY™ CL100S resin
|
SABIC_IP
|
|
PBT+PC
|
XENOY™ IQ1103 resin
|
SABIC_IP
|
|
PBT+PC
|
XENOY™ IQNH2900 resin
|
SABIC_IP
|
|
PBT+PC
|
XENOY™ X4850 resin
|
SABIC_IP
|
|
PBT+PC+PET
|
XENOY™ X5601WX resin
|
SABIC_IP
|
|
PBT+PET
|
4DUR® 9KL22120
|
|
|
PBT+PET
|
4DUR® 9KL22130 FR1
|
|
|
PBT+PET
|
Arnite® TM4 440
|
DSM Engineering Plastics
|
|
PBT+PET
|
Arnite® TV4 460 KL
|
DSM Engineering Plastics
|
|
PBT+PET
|
Arnite® TV4 461 KL
|
DSM Engineering Plastics
|
|
PBT+PET
|
Arnite® TZ4 254 S ((PBT+PET)-(GF+MD)25 FR(17), DSM)
|
DSM Engineering Plastics
|
|
PBT+PET
|
ASTAPET™ MDA282
|
Marplex Australia Pty. Ltd.
|
|
PBT+PET
|
Bergadur™ PB40 G25 BK035
|
PolyOne Corporation
|
|
PBT+PET
|
BESTDUR TPHG6/02
|
Triesa Plastics
|
|
PBT+PET
|
CompaDur® 125 GF 15 black (042)
|
DimeLika Plast GmbH
|
|
PBT+PET
|
CompaDur® 125 GF 15 natural (014)
|
DimeLika Plast GmbH
|
|
PBT+PET
|
CompaDur® 125 GF 20 black (045)
|
DimeLika Plast GmbH
|
|
PBT+PET
|
CompaDur® 125 GF 30 black (046)
|
DimeLika Plast GmbH
|
|
PBT+PET
|
CompaDur® 125 GF 30 natural (016)
|
DimeLika Plast GmbH
|
|
PBT+PET
|
DESOX™ DSC640G10
|
DESCO Co., Ltd.
|
|
PBT+PET
|
DESOX™ DSC640M5
|
DESCO Co., Ltd.
|
|
PBT+PET
|
DURANEX® 756HA
|
Polyplastics Co., Ltd.
|
|
PBT+PET
|
DURANEX® C5330N
|
Polyplastics Co., Ltd.
|
|
PBT+PET
|
DURANEX® CN7740XB
|
Polyplastics Co., Ltd.
|
|
PBT+PET
|
Durethan® T 7141 00000
|
multiple manufacturers
|
|
PBT+PET
|
EPIMIX PBT/PET GFU 30 NC
|
EPSAN Plastik SAN. ve TiC. A.S.
|
|
PBT+PET
|
ESTOPLAST MG 3020
|
Ester Industries Ltd.
|
|
PBT+PET
|
Generic PBT+PET - Glass Fiber
|
Generic
|
|
PBT+PET
|
Infino AR-6508
|
Samsung
|
|
PBT+PET
|
Kepex® 3715GF
|
KEP
|
|
PBT+PET
|
Kepex® 3730GF
|
KEP
|
|
PBT+PET
|
KumhoSunny PBT/PET HEB4050M
|
Shanghai KumhoSunny Plastics Co., Ltd.
|
|
PBT+PET
|
Lupox® SG3180S
|
LG Chem
|
|
PBT+PET
|
Lupox® SG3250M
|
LG Chem
|
|
PBT+PET
|
Lupox® SG5152
|
LG Chem
|
|
PBT+PET
|
Lupox® SG5300
|
LG Chem
|
|
PBT+PET
|
Melos PBT PB70 GR20 NL CA 01
|
Melos
|
|
PBT+PET
|
Melos PBT PB70 GR30 NL XA 21
|
Melos
|
|
PBT+PET
|
Petlon R-Prime M3-G30-00-BK
|
Petlon Polymers Ltd
|
|
PBT+PET
|
POCAN® ECO T 3215 000000
|
LANXESS
|
|
PBT+PET
|
POCAN® ECO T 3230 000000
|
LANXESS
|
|
PBT+PET
|
POCAN® KU 1-7313 000000
|
LANXESS
|
|
PBT+PET
|
POCAN® T 7141 000000
|
LANXESS
|
|
PBT+PET
|
POCAN® T 7323 POS151 000000
|
LANXESS
|
|
PBT+PET
|
POCAN® T 7331 POS151 700226
|
LANXESS
|
|
PBT+PET
|
POCAN® T 7391 POS151 900044
|
LANXESS
|
|
PBT+PET
|
Radici Compounds PBET500G30L
|
RadiciPlastics
|
|
PBT+PET
|
SCHULADUR® A1 GF 30 HF FR 1
|
A. Schulman
|
|
PBT+PET
|
SCHULADUR® A1 GF 50
|
A. Schulman
|
|
PBT+PET
|
SCHULADUR® PCR GF 15 K2027
|
A. Schulman
|
|
|
|
